000B48 |
Christine Archambault [France] ; Robert Bender [France] ; Pierre Braunstein [France] ; Salah-Eddine Bouaoud [Algérie] ; Djemel Rouag [Algérie] ; Stéphane Golhen [France] ; Lahcène Ouahab [France] | Unexpected bonding similarities between the bridging metalloligands [MoCp(CO)3]− and [PtI(CO)2(PPh3)]− acting as 4-electron donors in metal clusters. Crystal structures of [Pt2Mo(μ-CO)3- (μ-PPh2)Cp(PPh3)2] and [Pt3(μ-CO)2(μ-PPh2)I(PPh3 )3]Electronic supplementary information (ESI) available: preparation of 2, 3 and 5. See http://www.rsc.org/suppdata/cc/b1/b101410m/In memoriam Luigi M. Venanzi, who contributed so much to inorganic and cluster chemistry. |